Ultrafast laser pulses shed light on elusive superconducting mechanism

An international team that includes University of British Columbia physicists has used ultra-fast laser pulses to identify the microscopic interactions that drive high-temperature superconductivity.

In the experiment, to be outlined this Friday in the journal Science, electrons in a prototypical copper-oxide superconductor were excited by extremely short 100-femtosecond laser pulses.

As the material's electrons relax back to an equilibrium state, they release their excess energy via deformation of the superconductor's atomic lattice (phonons) or perturbation of its magnetic correlations (spin fluctuations).

The researchers were able to capture very fine grained data on the speed of the relaxation process and its influence on the properties of the superconducting system, showing that the high-critical temperature of these compounds can be accounted for by purely electronic (magnetic) processes.

"This new technique offers us our best window yet on the interactions that govern the formation of these elusive superconducting properties--both across time and across a wide range of characteristic energies," says UBC Associate Professor Andrea Damascelli, Canada Research Chair in Electronic Structure of Solids with the Department of Physics and Astronomy and the UBC Quantum Matter Institute.

"We're now able to begin to disentangle the different interactions that contribute to this fascinating behavior."

Superconductivity--the phenomenon of conducting electricity with no resistance--occurs in some materials at very low temperatures. High-temperature cuprate superconductors are capable of conducting electricity without resistance at temperatures as high as -140 degrees Celsius.

The key mechanism that allows the carriers to flow without resistance in superconductors stems from an effective pairing between electrons. In conventional metallic superconductors, this pairing mechanism is well understood as phonon-mediated. In copper-oxides, the nature of the low-resistance interaction between the electrons has remained a mystery.

"This breakthrough in the understanding of the puzzling properties of copper-oxides paves the way to finally solving the mystery of high-temperature superconductivity and revealing the key knobs for engineering new superconducting materials with even higher transition temperatures," says the paper's lead author Claudio Giannetti, a researcher with Italy's Università Cattolica del Sacro Cuore and visiting professor at UBC's Quantum Matter Institute.

The international collaboration also involved contributions from Japanese, Swiss and American researchers.

More information: "Disentangling the Electronic and Phononic Glue in a High-Tc Superconductor," by S. Dal Conte, et al., Science.

Light turns insulator into a superconductor

The team from Oxford, Germany and Japan are said to have observed conclusive signatures of superconductivity after hitting a non-superconductor with a strong burst of laser light. (D. Fausti et al., "Light-Induced Superconductivity in a Stripe-Ordered Cuprate", Science v.331, p.189 (2011)).

Abstract: One of the most intriguing features of some high-temperature cuprate superconductors is the interplay between one-dimensional “striped” spin order and charge order, and superconductivity. We used mid-infrared femtosecond pulses to transform one such stripe-ordered compound, nonsuperconducting La1.675Eu0.2Sr0.125CuO4, into a transient three-dimensional superconductor. The emergence of coherent interlayer transport was evidenced by the prompt appearance of a Josephson plasma resonance in the c-axis optical properties. An upper limit for the time scale needed to form the superconducting phase is estimated to be 1 to 2 picoseconds, which is significantly faster than expected. This places stringent new constraints on our understanding of stripe order and its relation to superconductivity.

‘We have used light to turn a normal insulator into a superconductor,’ said Prof Andrea Cavalleri of the Department of Physics at Oxford University and the Max Planck Department for Structural Dynamics, Hamburg. ‘That’s already exciting in terms of what it tells us about this class of materials. But the question now is can we take a material to a much higher temperature and make it a superconductor?’

The material the researchers used is closely related to high-temperature copper oxide superconductors, but the arrangement of electrons and atoms normally act to frustrate any electronic current.

In the journal Science, they describe how a strong infrared laser pulse was used to perturb the positions of some of the atoms in the material. The compound, held at a temperature just 20 degrees above absolute zero, almost instantaneously became a superconductor for a fraction of a second, before relaxing back to its normal state.

Superconductivity describes the phenomenon where an electric current is able to travel through a material without any resistance.

High-temperature superconductors can be found among a class of materials made up of layers of copper oxide, and typically superconduct up to a temperature of around –170°C. They are complex materials where the right interplay of the atoms and electrons is thought to ‘line up’ the electrons in a state where they collectively move through the material with no resistance.

‘We have shown that the non-superconducting state and the superconducting one are not that different in these materials, in that it takes only a millionth of a millionth of a second to make the electrons ‘synch up’ and superconduct,’ said Professor Cavalleri. ‘This must mean that they were essentially already synched in the non-superconductor, but something was preventing them from sliding around with zero resistance. The precisely tuned laser light removes the frustration, unlocking the superconductivity.’

The advance immediately offers a new way to probe with great control how superconductivity arises in this class of materials.

The researchers are hopeful it could also offer a new route to obtaining superconductivity at higher temperatures. If superconductors that work at room temperature could be achieved, it would open up many more technological applications.

‘There is a school of thought that it should be possible to achieve superconductivity at much higher temperatures, but that some competing type of order in the material gets in the way,’ said Prof Cavalleri. ‘We should be able to explore this idea and see if we can disrupt the competing order to reveal superconductivity at higher temperatures. It’s certainly worth trying.’